Engineering magnetism and thermal expansion in BiFeO3 for next-generation memory devices (Prof. Masaki Azuma, Assis. Prof. Takumi Nishikubo, Assis. Prof. Kei Shigematsu)
Using a dual-cation substitution approach, researchers at Science Tokyo introduced ferromagnetism into bismuth ferrite, a well-known and promising multiferroic material for next-generation memory technologies. By replacing ions at both the bismuth and iron sites with calcium ions and heavier elements, they modified the spin structure and achieved ferromagnetism at room temperature. Additionally, negative thermal expansion was observed. This ability to engineer magnetism and thermal expansion in a multiferroic material aids in realizing future memory devices.
| For details | Science Tokyo News |
| Authors | Kano Hatayama, Jun Miyake, Daiki Ono, Yusuke Shiono, Takumi Nishikubo, Koomok Lee, Shogo Wakazaki, Hena Das, Kei Shigematsu, Tomoko Onoue, Ko Mibu, Shogo Kawaguchi, Takafumi Yamamoto and Masaki Azuma |
| Title | Achieving Canted-Spin Weak Ferromagnetism and Negative Thermal Expansion in A- and B-Site-Substituted Bismuth Ferrite |
| Journal | Journal of the American Chemical Society |
| DOI | 10.1021/jacs.5c12255 |
| Related articles, websites | Science Tokyo website: Science for All “A new material for next-generation memory—with the surprising property of shrinking when heated“ |